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Continuity of electric displacement across liquid/liquid boundary

I'm trying to model an interface between two immiscible electrolyte solutions (interface of oil phase and aqueous phase). I have 1D system and I'm currently using Nernst-Planck application modes, one...

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Electrochemistry - Where are the reaction equations

I am writing a model involving chemical dissolution of a metal by an etchant. In order to do this, I wrote a steady state model (tertiary distribution w/ Nernst Plank, tcdee) that looks at an electrode...

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Semiconductor photoelectrolysis

Hello, I am hoping to model a photoelectrochemical cell in which a semiconductor working electrode (e.g. InP) is used in conjunction with a counter electrode (e.g. Pt) which under the influence of...

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Butler-Volmer kinetics

As an electrochemist I cannot understand the formulation of the equation of the electrode reaction kinetics (attached). Why is there (n - eta) in the first exponent, instead of 1- eta? The formulation...

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Simulating bipolar electrodes, problems with coupling transport and electric...

Hey, I'm trying to simulate a system in 1D where a slab of metal surrounded from both sides by a liquid and subjected to electric field. I use Transport of Dillute Species in liquid phases, and tried...

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Continuity of electric displacement across liquid/liquid boundary

I'm trying to model an interface between two immiscible electrolyte solutions (interface of oil phase and aqueous phase). I have 1D system and I'm currently using Nernst-Planck application modes, one...

View Article

Electrochemistry - Where are the reaction equations

I am writing a model involving chemical dissolution of a metal by an etchant. In order to do this, I wrote a steady state model (tertiary distribution w/ Nernst Plank, tcdee) that looks at an electrode...

View Article

Semiconductor photoelectrolysis

Hello, I am hoping to model a photoelectrochemical cell in which a semiconductor working electrode (e.g. InP) is used in conjunction with a counter electrode (e.g. Pt) which under the influence of...

View Article


Butler-Volmer kinetics

As an electrochemist I cannot understand the formulation of the equation of the electrode reaction kinetics (attached). Why is there (n - eta) in the first exponent, instead of 1- eta? The formulation...

View Article


Simulating bipolar electrodes, problems with coupling transport and electric...

Hey, I'm trying to simulate a system in 1D where a slab of metal surrounded from both sides by a liquid and subjected to electric field. I use Transport of Dillute Species in liquid phases, and tried...

View Article
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